A worker exposed for several days to concentrations of chromic acid mist of about 20 to 30 mgm 3 equivalent to about 10 to 15 mg crvim 3 experienced cough, headache, dyspnea, and substernal pain. The ester forms by nucleophilic attack of the alcohol oxygen atom on the chromium atom. Acetic acid is incompatible with chromic acid, nitric acid, ethylene glycol, p erchloric acid, phosphorous trichloride, oxidizers, sodium peroxide, strong caustics, mos t metals except aluminum, carbonates, hydroxides, oxides, and phosphates. The technical grade is obtainable from primary producers in an anhydrous form as small dark red flakes containing 99% cro3. Cdc niosh pocket guide to chemical hazards chromic acid. Using extreme caution, it is possible to make a chromic acid cleaning solution at home. Hazard identification very hazardous in case of skin contact irritant, of eye contact irritant, of ingestion. Use of gastric lavage or emesis is contraindicated.
Material safety data sheet chromic acid section 1 t3db. Chromic acid may also refer to the molecular species, h 2 cro 4 of which the trioxide is the anhydride. Hazardous to aquatic environment long termchronic category 1. Fisher scientific 1 reagent lane fair lawn, nj 07410 for information, call. Chemtrec 8004249300 outside usa 7035273887 msds number. The term chromic acid is usually used for a mixture made by adding concentrated sulfuric acid to a dichromate, which may contain a variety of compounds, including solid chromium trioxide. Chromic anhydride definition is a brilliant red crystalline substance essentially cro3 that is made from sodium dichromate and sulfuric acid and that is used especially in chromium plating and as an oxidizing agent called also chromium trioxide, chromic acid. Safety data sheet creation date 24nov2010 revision date 29jan2018 revision number 3 1. Duration of exposure, concentration of the substance. Identification of the substancepreparation and of the companyundertaking ghs product information product name.
Chromic acid is found on list a, which contains most pesticides that are used on foods and, hence, have a high potential for human exposure. Chromium trioxide solution to 15% material safety data sheet. Chromic acid and chromates centers for disease control and. Dscl eec all ingredients are listed on the dscl inventory. Chromic acid, 10% wv safety data sheet according to federal register vol. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet emergency telephone number chemtreco, inside the usa.
Sverre langard, max costa, in handbook on the toxicology of metals fourth edition, 2015. Chromic acid flake business unit phibrochem other means of identification. Jul 17, 2017 chromic acid is not a popular cleaning solution, because chromium is classified as a carcinogen. Ii section 15 regulatory information us federal tsca. Chromic acid flake issue date 11102015 revision number 5 safety data sheet 1. Chemical product and company identification product name. This important acid is known also as chromium trioxide.
Chromium trioxide solution to 15% material safety data sheet integra chemical company 24 hour emergency response. This product contains a chemical known in the state of california to cause cancer. Inhalation of dust containing chromate or chromic acid fumes is reported by a number of authors to result in bronchial asthma, with most authors reporting a lag time of 48 h between exposure to crvi compounds and the asthmatic attack joules, 1932. Persons with preexisting skin disorders, asthma, allergies or known sensitization to chromic acid or chromates may be. Persons with preexisting skin disorders, asthma, allergies or known sensitization to chromic acid or chromates may be more susceptible to the effects of this material. Occupational exposure limits osha table z1 limits for air contaminants chromium trioxide 33820 twa 0. Material safety data sheet chromic acid 6 section 14 transport information us dot shipping name. Chromic acid is an intermediate in chromium plating, and is also used in ceramic glazes, and colored glass. Identification product name chromerge cleaning solution cat no. Tdg un1755, chromic acid solution, 8, pg ii imdg un1755, chromic acid solution, 8, pg ii marine pollutant yes iataicao un1755, chromic acid solution, 8, pg ii. Because of the low vapor pressure, inhalation is unlikely to be a problem with this product.
Chromic oxides gas may form if decomposition occurs. Section 1 chemical product and company identification. Uses advised against details of the supplier of the safety data sheet emergency telephone number chemtreco, inside the usa. Chromic acid cleaning solution 500 ml for cleaning glassware on sp510 hardness analyzer for cleaning glassware no dilution necessary. Wear a selfcontained breathing apparatus scba to prevent contact with thermal decomposition products. Possible perforation of stomach or esophagus should be investigated. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy.
Chromium trioxide, chromic anhydride, monochromium trioxide. Because a solution of chromic acid in sulfuric acid also known as a sulfochromic mixture or chromosulfuric acid is a powerful oxidizing agent, it can be used to clean laboratory glassware, particularly of otherwise insoluble organic residues. Another man working on the same process was similarly but less severely affected ilo 1971. Chromic acid h 2 cro 4 reacts with alcohols to form a chromic ester in which the alcohol oxygen atom bridges the carbon and chromium atoms. Identification product name chromium trioxide cat no. May cause severe and permanent damage to the digestive tract. Safety data sheet chromic acid flake date prepared.
Material safety data sheet chromic acid 2 chromium compounds has been shown to be associated with lung cancer and gastrointestinal tract tumors. Regulatory information tsca inventory status all ingredients are listed on the tsca inventory. List a consists of the 194 chemical cases or 350 individual active ingredients for which epa issued registration standards prior to fifra 88. Chromic acid cleaning solution 500 ml for cleaning glassware. Chromic acid is toxic and should be made in small quantities and stored in a labeled glass. Chromic anhydride definition of chromic anhydride by.
It is still used occasionally despite the careful handling that it requires because it is effective at removing cloudy stains from glass that no other cleaner does. G4099, g5099, g6099, g8599, g112, g120, m100, ga4090, ga6090 accrox r, accrox s, accrox c, chromium oxide metallurgical chemical formula. This chemical is considered hazardous by the 2012 osha hazard communication standard 29 cfr 1910. Radchem cc po box 166982 brackendowns alberton 1454 telephone. Chromic anhydride recommended use laboratory chemicals. How to make a chromic acid cleaning solution hunker. This chemical is considered hazardous by the 2012 osha hazard communication. Bath temperature indicate the bath temperature in degrees fahrenheit tank process indicate the operation occurring in the tank e. Product code 2028200 chromic acid flake revision date 11102015 note to physicians. S799641 synonyms none recommended use laboratory chemicals. This kind of chromic acid may be used as a cleaning mixture for glass.
H411 toxic to aquatic life with long lasting effects. This chemical is considered hazardous by the 2012 osha hazard communication standard 29. Material safety data sheet chromic acid, 10% msds section 1. Material safety data sheet chromic acid labchem inc. Material safety data sheet chromic acid 3 appropriate protective clothing to prevent contact with skin and eyes. Noncombustible solid, but will accelerate the burning of combustible materials. Combustible, organic, or other readily oxidizable materials paper, wood, sulfur, aluminum, plastics, etc.
Chromic acid page 2 of 6 this fact sheet is a summary source of information of all potential and most severe health hazards that may result from exposure. Industrial, manufacturing or laboratory use manufacturer. Uses advised against details of the supplier of the. Specific target organ toxicity repeated exposure category 1 causes damage to organs.
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